Ruben Neves scored the decisive spot kick after Alvaro Morata missed as Portugal beat Spain 5-3 on penalties following a 2-2 draw in Munich on Sunday to claim their second Nations League title.
Reigning champion Alcaraz rallied from the brink of defeat to overcome world number one Sinner 4-6, 6-7 (4/7), 6-4, 7-6 (7/3), 7-6 (10/2) to clinch his fifth Grand Slam title after five hours and 29 minutes.